As unsatisfying of an answer as this is, for the most part this is just practice. I think everyone starts off throwing wonky sleepers and breakaways when they first start, it just takes practice to get them consistently straight.
This could be a that the strings aren’t lined up straight and are rubbing against the response. Try it again and look closely at what the strings are doing when you’re throwing a brain twister. If they’re off center and you’re applying pressure then the yoyo will naturally gyro-flop off its axis, everything needs to be kept in a straight line in order to keep the yoyo straight.
With practice you should be able to get binds at very low RPMs, even on a throw with a wearing response. Mind if I ask what yoyo you’re using? If you’re using a Yoyofactory then you can swap the standard white pads out for something like the natural pads that are a bit more grippy so will be easier to bind with if you’re having that much trouble.
As far as binding at slow speeds goes, watch the final bind of this video:
What Clint does if you look carefully is that as he binds he doesnt just drop the yoyo and leave it to return to his hand, he pulls it up into the air and then moves his hand closer to it so that it can pick up the slack easier. Its hard to describe but if you study it you’ll see that it can be done with very little spin because it’s somewhat weightless in free-flight so doesn’t need the same momentum to wind itself up against it’s hanging weight.
Its very hard to say exactly what the problem is since we don’t have a video or anything. At any rate, when I started it took me ages to learn to throw straight and even longer to learn to bind consistently. Just keep at it and eventually you’ll get it… just wait till you start learning magic drop or brent stole…