I can’t really say 5, cuz this might be a bit of a weird question.
I’d say the further throws would all be much more recent, as the first yo could easily just be rock/bone tied to some twine, but the Duncan butterfly and modern ball bearings are both drastic changes to what yoyos have been for ages.
Just my two cents, maybe I’m just not trying hard enough to think of a solid list.
edit: I’m an idiot, people had much nicer things by 1950, should have read better.
I definitely think if the not just the popularity of the Duncan butterfly is enough for it to be on the list, maybe the Free Hand Zero for how much innovation that that yoyo brought around when ball bearings were first getting real popular.